Organic pigment Blue 15, Cu-Phthalocyanine 17nm, hydrophobic
identification on basis of all expected peaks in the range (PDF 00-062-09377). Partly amorphous. Size of crystalline domains (spherical approximation): 11.0±4.9; size of crystalline domains (elliptical approximation):7.9±1.2 nm and 19.3±0.2 nm (from 8 peaks in the range 10-30°)
Material: α-copperphthalocyanine. Crystal structure: triclinic, degree of crystallinity: 82% (via analysis software)
hotplate digestion for 90 minutes + UKAS 3504-ICP-MS SOP
elemental composition and chemical purity
identifaction on basis of all expected peaks in the range (PDF-01-072-1387). Size of crystalline domains: 14.9 ± 2.3 nm (10 peaks 20-60°)
Material: barium sulphate. Crystal structure: orthorombic
saliva (5 mins) +stomach (120 mins)+ intestine (120 mins)
Identification on basis of all expected peaks in the range (PDF 01-077-6683). Size of crystalline domains: 5.9±0.9 nm (4 peaks 30-80°)
Material: silver. Crystal structure: cubic
Ag NM-300K 10 w/w%, <20 nm, 4% w/w% each of Polyoxyethylene Glycerol Trioleate and Polyoxyethylene (20) Sorbitan mono-Laurat (Tween 20).
NanoDefine Deliverable 6.3 (2017) "Measurement of the minimal external dimension of the primary particle of particulate materials from TEM images by the NanoDefine ParticleSizer software". NanoDefine SOP 5.1 (2016) "Nanoparticle size characterization in
saliva (5 mins) +stomach (120 mins)+ intestine (30 mins)
Silicon dioxide, Al substituted into the surface, aggregated nanoparticles, 7% total solids, pH 8.5
MWNT with small amount of impurities (amorphous carbon, debri, catalyst and so on)
Crystallinity 48.5 ± 5.82 % Crystal structure: Cellulose I
Organic pigment Red 254 opaque, diketopyrrolopyrrole, 230nm, borderline hydrophobic
NM-212 Cerium (IV) Oxide precipitated, uncoated
identifaction on basis of all expected peaks in the range (PDF 01-080-3726). Size of crystalline domains: 20.4± 0.3 nm (6 peaks 20-80°)
Material: Cerium oxide. Crystal structure: cubic (cerianite)
WP5-What they do: Human and environmental toxicology
Organic pigment Green 7, CuPhthalocyanine 14nm hydrophobic
Identification on basis of peaks matched by PDF 00-036-1870 and PDF-00-036-1871. Partly amorphous. Size of crystalline domains (spherical approximation): 19.8 ±1.6 nm (10 peaks in the range 10-40°)
Material: pigment green 7 + pigment green 36. Crystal structure: triclinic. Degree of crystallinity = 72% (via analysis software)
Inorganic pigment Red 101, rods, hydrophilic
identification on basis of all expected peaks in the range (PDF 01-073-8432). Size of crystalline domains (spherical approximation): 8.7±4.0; size of crystalline domains (elliptical approximation): 6.2±1.2 nm and 15±0.7 nm (from 7 peaks in the range 30-65°)
Material: Iron(III) oxide. Crystal structure: Rombo.H.axes, degree of crystallinity = 95% (via analysis software)
organic pigment Red 254 opaque, diketopyrrolopyrrole, 233nm, hydrophobic
organics (calibrated by fully dissolved pigment in conc. H2SO4)
KRÜSS Technical Note TN306e, C. Rulison, 1999,
Identification on basis of all expected peaks in the range (PDF 01-077-6683). Size of crystalline domains (spherical approximation): 12.7±6.2; Size of crystalline domains (elliptical approximation): 23.4 x 9.2±1.0 nm.
NM-200 Synthetic Amorphous Silica PR-A-02
Silicon dioxide, Standard silica, aggregated nanoparticles, 12% SiO2, pH 11
Trace metal analysis in colloidal silica by ICP-MS after sample dilution and addition of HF
identification on basis of all expected peaks in the range (PDF 00-055-1984). Partly amorphous. Size of crystalline domains (spherical approximation): 11.2± 2.6nm (from 7 peaks 15-35°)
Material: 3,6-bis(4-chlorophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione]. Crystal structure: monoclinic (found by comparing spectra with literature), degree of crystallinity: 64%
organic pigment Red 254 transparent, diketopyrrolopyrrole, 43nm, hydrophobic
Silicon dioxide, Al substituted into the silica surface, 25%
Inorganic pigment Red 101, 37nm, hydrophilic
identification on basis of all expected peaks in the range (PDF 01-073-8432). Size of crystalline domains: 23.4±0.5 nm (from 7 peaks in the range 30-65°)
Identification on basis of all expected peaks in the range (PDF 01-077-6683). Size of crystalline domains (spherical approximation): 13.7±3.4; Size of crystalline domains (elliptical approximation): 19.6 x 11.7±0.5 nm.
Electrospray Differential Mobility Analysis (ES-DMA)
Trace element analysis in colloidal silica by ICP-OES
activation of Nrf2 antioxidant response pathway
PARTICLE SIZE CHARACTERIZATION IN COLLOIDAL SILICA EXP320 USING DYNAMIC LIGHT SCATTERING
Cellulose nanofibrils 80 nm diameter x 6.6 µm length
ZnCuInS/ZnS-COOH_larger, hydrophilic (700nm)
In-house KRISS SOP which was established according to suggested requirements in ISO 17025 (General requirements for the competence of testing and calibration laboratories), and technically to JIS K 0131 (General rules for X-ray diffractometric analysis)
Journal of Physics: Conf. Series 838 (2017) 012033
SPECIFIC SURFACE AREA IN COLLOIDAL SILICA
NM-211 Cerium (IV) Oxide precipitated, uncoated, cubic
Cellulose nanofibrils 50 nm diameter x 6.6 µm length
ISO, 2015. OECD (2015c). NANOGENOTOX D4.2 (2012) "Transmission electron microscopic characterization of NANOGENOTOX nanomaterials" https://www.anses.fr/en/system/files/nanogenotox_deliverable.2.pdf
NM-111 Zinc Oxide coated triethoxycaprylsilane
NM-203 Synthetic Amorphous Silica PY-A-04
NANOGENOTOX D4.2 (2012) "Transmission electron microscopic characterization of NANOGENOTOX nanomaterials" https://www.anses.fr/en/system/files/nanogenotox_deliverable.2.pdf
identifaction on basis of all expected peaks in the range (PDF 00-055-1984). Partly amorphous. Size of crystalline domains (spherical approximation): : 20.4±1.6 nm (from 6 peaks 15-35°)
Material: 3,6-bis(4-chlorophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione]. Crystal structure: monoclinic (found by comparing spectra with literature), degree of crystallinity: 75% (via analysis software)
ZnCuInS/ZnS-COOH_smaller, hydrophilic (530nm)
identification on basis of all expected peaks in the range (PDF 00-055-1984). Partly amorphous. Size of crystalline domains (spherical approximation): 20.9±1.9 nm (from 6 peaks 15-35°)
Material: 3,6-bis(4-chlorophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione]. Crystal structure: monoclinic (found by comparing spectra with literature), degree of crystallinity: 74% (via analysis software)